Larger tanks tend to have slightly thicker silicone between the panels. It's a bit of work, but if you're systematic about it, it shouldn't take long. My son and I dismantled an old 125 in about an hour this past spring.
The key is to remove the inner silicone bead completely That means running a straight edge razor down the two sides that make up each corner. If you go right to the inner corner with each pass you'll remove each silicone bead with two quick passes of a straight razor.
The tough part is seperating the panels. If the silicone between the panels is thick enough to be visible, you should be able to run a utility knife all the way down the seam, albeit with some effort. If it's a very thin seam of silicone between the panels you'll have to be more creative. Some have used thin gauge wire strung between two pairs of pliers and simply forced downward though the seam. Once you manage to force wire, a blade or anything into the very top of the seam, you need to insert something just slightly thicker right behind it in the seam. This makes forcing whatever you've chosen to cut through through the seam, a real breeze.
Also don't be fooled into thinking you can handle one of those panels by yourself. The half inch panels of the 125 I dismantled were quite heavy. The large panels of a 500G should take at least 4 people to handle safely.
Also, I don't know of anyone that you can find to do this for you. I guess you might get an aquarium maintenance company to give it a try, but you'll pay by the hour for sure, and cost you a good penny. Just guessing on this one though. If you do find someone, I'd be curious of who would undertake this.
Finally, I don't know of anything that removes cured silicone. Acetone may do it before it cures, but on an old tank like this, I think it's pretty useless.