A while back i played around with dosing iron Citrate and ended up with some overgrowth of bacteria and some STN of acropora corals(I had an overdose). I decided to reset the tank using the Zeovit system and have discovered that it is similar to what I was doing with nitrate in the first place.
The system consists of Zeolites in a reactor, and daily doses of a "Carbon source" called ZeoStart. You also dose bacteria daily when the stones are first set up, then a couple of times per week for maintenance later.
Anyhow, what I have discovered is that Zeostart is both a carbon
and nitrate source. The carbon is very concentrated, possibly glacial acetic acid or acetate or a combination of both, and the nitrate is very concentrated as well(approx 500ppm). The system only requires a very small addition(~2ml/250Gallons per day) so it has the same effect of adding small amounts of nitrate in a carbon dosing tank.
Now about the Zeolites - An analysis was done on the stones to see what they adsorbed. That analysis was very interesting, it shows that the stones appear to
leach Titanium, Manganese, Rubidium, Sulphur, and Strontium in small amounts and leach Iron and Calcium in larger amounts. As discussed here on this thread, Iron and Manganese may be two important elements to get bacteria to grow that people overlook. The analysis also shows that the stones don't adsorb Phosphate, but do adsorb a bit of Potassium, hence the need to add Potassium back. Phosphate removal is just performed by the bacteria like many other carbon dosing systems.
A lot of emphasis in Zeovit is on how much Zeolite to use and how fast to flow water through the Zeolites. The stones themselves are a great growth location for bacteria as the amount of these trace elements at the stone itself is high and it makes for ideal conditions for the bacteria to grow. Flow too fast or use too much and too much of the trace elements leach into the tank and STN occurs.
To be clear, I am not trying to push Zeovit, I just find the similarities between the systems to be very interesting.
I think all these systems come down to the same basic requirements to keep bringing down phosphate:
Bacteria
Carbon
Slight excess of Nitrate
Iron and possibly Manganese
Efficient skimming to remove the bacteria.
Probably a similar effect could be generated by dosing small amounts of iron and manganese along with mixture of vinegar and nitrate - broken up into small doses per day would be ideal.
To look at the analysis yourself:
http://www.teichratgeber.de/meerwasser/index2.html
Click on the "Analyse 7: ..." link then navigate to the Zeovit tests to see the elemental analysis. Its easier if you feed it through google translate.