it sounds like your fish are reacting to something in the change water and as it dilutes out they're settling down. with everything the same for years and then this behavior consistently, i'd suspect some contamination. either a bad batch of salt, or the buffer you're using, or your mix container. maybe someone innocently used one of your buckets to wash the car or mop the floors.
two things i don't like here, one is the water you are using. you have no control over the quality of it, maybe someone cleaned the equipment at walmart's distilled water supplier, or they got a new batch of bottles from china... water is so critical, i'd recommend taking your fate into your own hands and ponying up for an RO unit.
the other thing i don't like is the fact that you're using the water so soon after making it. 24-48 hours is fine in an emergency, but not as a habit. i'd stir it with a powerhead for that long and let it sit for at least a week before using it in general. i don't think this has anything to do with your current situation, but it fits into what my recommendation will be.
you need to get rid of the contamination immediately, and you should protect yourself from having it happen again. i would:
- go get a brand new brute trash can, 20 gallons if you don't have the space for the big one, write SALT WATER ONLY all over it and the lid. get the dolly with casters for it if you can fit that into your space, it makes life a lot easier. get two brutes if you have the space so you can use one just for top off water.
- go get an RO unit. if you get one with an auto shutoff, you can put a float valve in the lid of that trash can so you never have to worry about a flood.
- throw out the proper ph, it's unnecessary
- go get a fresh bucket of salt. if the problem is resolved by all of these actions, throw out the old salt.
good luck robin!