Why would anyone use plexiglass/acrylic instead of glass for this application? More expensive and much worse light transmission.
My tank top is a piece of glass I bought at HD and cut to order. I think it cost $8. Perfect light transmission, cheap, no holes for jumpers.
I hear the concerns about gas exchange but if you have a sump and a skimmer (and why wouldnt you?), you already have more than enough gas exchange.