Ca , alk and Mg are all related to each other and kind of tied together in a chemistry dance. I struggled for a long time as I hated chemistry (I'm a physics guy). You really don't need to worry about Ca yet. But after your tank is cycled and in the process of maturing (over the next 6 to 12 months) Ca, alk and Mg will all start to matter more and more. Measuring Ca without knowing what your alk and Mg levels are is almost useless unless you really know what you are doing and have a baseline history with your tank.
Ca and alk have a very direct relationship and a ratio that makes keeping them in the desired levels easier. Mg is also involved, but your system will use much less of it than Ca and alk. If you are going to keep LPS or sps corals these 3 are the building blocks of how they make skeletons. Using a good rees quality salt like Instant Ocean Reef Crystals rather than a fish only type salt like basic IO will help. Your water changes will keep you in the ballpark until you have more coral, then you will need to add all 3 by dosing, using a Ca reactor or using Kalkwasser.