If you want your mandy to take frozen well, I think the best thing to do is train them in a small tank or breeder net.
Check out this link.
http://en.microcosmaquariumexplorer.com/wiki/Breeding_the_Green_Mandarin
Quote:
Secrets of Mandarin Feeding
In order for mandarins to thrive in a captive environment, they must be supplied with sufficient high-protein foods.
There are two commonly approached methods and one certainly produces better long term results. It has long been said that in order for mandarins to survive, a large, mature, rock-filled aquarium was needed. The idea being that harpacticoid copepod populations present on a large surface area of live rock would support the near-constant foraging behavior of this fish.
While this method can work to support the dietary demands of a mandarin, it is far too prone to failure in closed systems. (Aquarists often over-estimate the productivity of their reef systems or stock species that compete for the limited crops of microfauna.)
Refugiums help support copepod populations, but all too often mandarins slowly suffer from starvation in such settings. A much more realistic and successful approach involves weaning mandarins off a strictly live food diet and teaching them to accept frozen foods, such as mysis shrimp, that are readily available.
The best method in my opinion was developed by Matt Pedersen of MOFIB (see the links below). The idea is quite simple. Isolate new mandarins in suspended breeder baskets (or small quarantine tanks) and get them feeding on enriched live brine shrimp. Then, introduce frozen brine shrimp and mysis shrimp. After the fish begin sampling the frozen fare the live diet is slowly replaced. Once they are eating frozen fare with vigor they are released into the display tank where their "training" pays off.