metal toxicity

reefmutt

Active member
Hi All,
I am wondering about metal toxicity in a reef and how much damage, let's say one penny in a 700 gallon system could go. Or maybe a 1 1/4 in dry wall screw.
I am wondering because I have a friend who is not a big computer user who has problems with mainly sps corals not surviving.
His system has been running for 4 years and is now situated on 3 floors of his home. Tank upstairs, tank main floor, sump in basement.
Originally, there were deep and old sand beds in the display and sump, recently the the sump was redone and the sand bed was discarded, there is still the oldest sand bed remaining in the display, but is is only about 3 inches at its deepest.
All parameters have been tested and retested- calc mag alk ph all have been monitored and now stay well within acceptable norms.
Temp and lighting have always been the same and flow has been increased lately.
Po4 and No3 are always not detected on salifert and elos kits- the system has a large sump full of macro algae, Still, GFO and carbon is run at all times.
The tank is full of large fish and gets heavily fed.
The light bulbs, calcium reactor and skimmer are always maintained..
Frequent smaller water changes had no effect on the slow decline and wasting away of sps, but massive water changes (aprox150-200g) have shown to have a temporary beneficial effect. Polyps extend and color improves, but after a few weeks, the corals begin to decline.
The latest attempt to deal with the problem has been the addition of a large amount of activated carbon instead of small frequently changed amounts.
We are toying with the idea of pulling out the sand bed in the display as a last ditch effort...
There is also a persistent tan colored goupy 'algae' here and there but not infesting the tank. I assume it is a diatom algae, there are no other problem algae in the tank.
But I am wondering about foreign objects, like a penny or a screw or something like that.
Would one penny give a copper reading in a test kit or would it require a hand full of pennies, how about a screw, or many screws??
I have not yet tested for copper, and don't even know if a standard copper test kit would be suitable for the low levels that occur in a reef..
I have no idea how much of one or another metal is required to cause slow decline in corals.
There are many other corals, like an established seriatopora , montipora confusa and fire coral that seem to grow and do fine and they have all been in the tank for years.
Newer additions seem to do the worst.
Any theories on metal toxicity or other would be greatly appreciated!
Thanks in advance!
 
I might suspect the fire coral and its toxins as a potential culprit for his problems, especially if the coral is fairly large. ;)

For concerns regarding heavy metals he can run a poly-filter which will change colors if high levels are present. The hobby grade heavy metal kits can only detect very high levels present.
 
Thanks for the link, I will go through it.
Poly filter is also an excellent idea..
As a matter of fact, the fire coral is absolutely enormous and continues to grow and spread faster than any other coral in the tank!!!
I had NO idea that fire coral, in particular, could be so toxic...
thanks again..
 
Thanks, Randy.
this sort of rules out the penny theory anyways, but not another metal..
I will look at your link as well.
 
If corals come into close contact with one another, then a lot of chemical warfare will take place. In these cases, good circulation and running plenty of GAC and changing it frequently may be your best option. Also, prunning the coral such that there is adequate space will help reduce the chemical warfare. Fire coral are not slackers in this department, as they have some of the more toxic chemical weapons. ;)

If your frend was lax for a while in water changes and changing (or not enough) carbon, then these chemicals could build-up to where they become a problem.
 
That fire coral takes up most of the back glass of his 300 gal tank and is by far the largest coral in the tank.

I would say that the carbon usage has been on the low side for quite some time..

This problem has been slowly cropping up over the past 6 months. I assumed by your numbers, Randy, that the tank would be a right off pretty quick with a penny in there.. I guess my next question is how fast would a penny dissolve in an old sand bed?

Forgot to mention that he has bubble tip anemones, regular green ones and a rose that are splitting continuously, which leads me to believe in a major stress in the water..
 
FWIW, when you use a calcium reactor, more heavy metals and such will be added to your tank, since this type of reactor does not allow these metals to settle out like when using kalk water. You want to use a good clean source for calcium reactors. ;)
 
I think starting the gac is a very good step. I second Cliff's recommendation for polyfilter. Cuprisorb may help too if it is metal toxicity. The gac will remove some organic materials. Elevated total organic carbon could be the culprit.
 
thanks,Tom.
the gac went in about 5 days ago, so I will check if it had any positive effects..
The poly filter, I will definitely add this week.
There is a beast of a skimmer on the system which pulls out huge quantities of skimmate continuously...
If I see the poly filter turning blue, I will try cuprisorb as well..
 
Small amounts of metals even copper wont always turn it blue. It's still good to use.Skimming is a good thing but gac will take out more organics in my opinion.

Good Luck
 
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