Thank you for the input Rython. Does that apply for a new tank as well?
Yes. That pukani will come with all kinds of dead stuff on it. You can rinse it and scrub it with a tooth brush, but it's very porous and will still have tons of decaying ocean organisms on/in it.
You can throw it in the tank and let it cure in there, but it can take weeks and will smell horrible (decay). And you'll have to do a lot of water changes to get all those nutrients out. That's why most people do it in a brut trash can outside ou on the garage. A powerheads and heater may speed it up.
You can also bathe the rock in mueratic acid, basically eating away the dead stuff, and the outer layer of the rock. I understand that speeds the process up considerably. You'll want to read up on that.
I'm not sure what you do about the phosphate leaching. You'll have to read up on that. I just know it's a downside to using pukani. But it's a popular rock, so people must have found a way to prepare it for use. Maybe the acid bath will do it.
The live sand is a similar deal. It's been sitting in a bag on a shelf. There is already a lot of die off. But since it's mostly microorganisms the die off isn't going to outweigh the filtration capacity of what's still alive. The dead will feed the living to some extent. But if you rinse it, you'll lose even more live bacteria. And you'll get rid of dead stuff too. But if you're going to do that, it begs the question, why not just buy dry sand and add bacteria in a bottle? Although if you aren't going to run a skimmer, it might still be the better choice, since you won't have a good way to pull that junk out of the water (other than lots of water changes).
Also, I wanted to make sure you know that you can run a protien skimmer without a sump. Many people have successful reefs with just rock, sand, a hang-on-back protien skimmer and water changes for filtration and nutrient removal. Protien skimmers are so effective that forgoing one is kind of "the hard way". But there are certainly many ways to do this, and I would never discourage anyone from trying it their own way. But this is an expensive hobby, so it's good to have a realistic idea of the challenges that lay ahead, so at least you're making informed choices.