Water change day and testing time...
Last tests where 3 days after wc, and today before the wc. The alkalinity dropped a lot. Is this normal in a tank with just a Xenia? Where is the alkalinity going. Could it be the Calcium pushing down the alk? I do not dose anything. I'm just guessing until I get a Calcium and pH test.
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is the test result before or after WC?... if after u may want to do another WC (40-50%) to bring NO3 down. Salinity is a bit high, I like to keep mine at 1.025. Temp is high too, I keep my tank at 25C.
what was Alk level previously? It means ur tank is using Alk and Yes if ur Calc level went up then Alk would go down as they interact with each other and vice versa (if Alk goes up, then Calc goes down) Bc they interact together, 2-part dosing of Alk & Calc should be done in equal parts. There's a never ending debate about this and people will argue this is not necessary, however I subscribe to this as do the manufacturers of 2-part dosing. So when people dose more Alk than Calc to bring Alk higher, it just ends up throwing the tank water more out of balance.
Everything in your tank uses calcium/alkalinity (calcium carbonate) in balance. It doesn't matter if it's being consumed by coralline algae, growing snails, growing SPS/LPS, or white deposits on your heater and water pumps. it is all one part calcium and one part carbon.
This is what I do to determine how much to dose 2-part; I measure a newly mixed batch of seawater's Alk & Calc readings, which becomes my target levels. Measure ur existing tank (that's full of coral n fish) water levels, the difference in Alk & Calc readings between newly mixed batch of seawater and ur existing tank water is the amount of Alk & Calc u will need to replenish via 2-part dosing.
Please read this very good article about 2-part dosing by Joe Jaworski
https://joejaworski.wordpress.com/2014/05/19/the-right-way-to-use-2-part-additives/
Dosing should start after ur tank has established itself and been running well for a month or so and not while it's still cycling or settling in.
Also, u can get a lot of info about coral requirements from Live Aquaria