Purple Tang

None, they get too large and rather aggressive, especially in a small tank. How about a dwarf angel like a coral beauty instead?
 
How many can I keep in a 65g tank?

Agree with the others. Not what you wanted to hear but these fish are extremely active, grow to a good size and are quite aggressive. A 65 would be terribly cramped for even a single one. A 6 foot tank would be a good starting point to keep one.
 
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