Well in order to product RO/DI water, the water must first go through the RO membrane then through the DI element. I would imagine there would be more resistance when making RO/DI water in comparison to just making RO water.
When making RO water, typically the water comes out of the membrane then through a carbon filter. I don't know if the carbon element has more resistance than a DI element.
That may be the reason ... if you are getting higher flow out of RO.