Many people do this. You can simply tap off of the RO line and fill some jugs like you do, but many people find it more convenient to have a reservoir with a separate tap.
Bulk Reef Supply has a system
here (you need to get a DI stage for this)
Buckeye Field Supply has an
add-on RO tank
I believe
Spectrapure and
the Filter Guys also sell equipment do do what you want.