Should I be vacuuming my sand to remove nitrates?
Well, it depends on grain size and what your using to suck up the water. If your using super fine sand, I'm not sure you'll be able to siphon it. I'm using Fiji pink and feel like if it was any smaller it'd be really hard to siphon. I bought one of these recently which works well, I just have to take it easy and lightly siphon:
Genuine TERAPUMP Aquarium Cleaner Aquarium Fish Tank Gravel Sand Cleaner with Long Nozzle N Water Flow Controller - BPA Free (model: TRFTCLN)
https://www.amazon.com/dp/B011DDJZ9Y?ref=yo_pop_ma_swf
It works fairly well but I'll still suck up some sand if I get too aggressive.
What I generally do is gently stir up the sand, just rake across it and the detritus usually stays on top or in the water column. I have a couple of areas where detritus gets trapped so I gently turkey bast those areas as well as my LR and again, the detritus stays on top of the sand or in the water column. Once I've done that, I'll siphon the sand lightly. I just keep an eye on it and if it starts sucking up too much sand, I back off for a bit. TBH, I don't mind sucking a small amount of the sand bed out every water change. Eventually, it'll get low enough and I'll just add more sand. I've always thought that "œold tank syndrome" is likely caused by sand and rock absorbing phosphates and other stuff over time until it can't, then it releases it back into the tank. So I try to keep my rock and sand as clean as possible. I feel like detritus is one of your worst enemies in a reef tank so I try to get out as much as possible. I kinda regret adding sand to my latest build even though I love the look and hate the look of BB, but it would be so much easier to suck out detritus in a BB or false bottom tank!
If you are using super fine sand, I'd just lightly stir or take across it, then siphon right above it. Just find the sweet spot where you're sucking up the detritus that's laying on the sand but not the sand itself. Your other option would be to stir the hell out of it and just siphon it out of the water column and then turn your pump back on and send the rest into your sump to be caught by a filter sock or similar and your skimmer. I do this every once and a while too and just create a detritus snow storm.