Initially, vinegar realees H dropping the ph. 20ml all at once for 350 gallons shouldn't and didn't have much effect but a larger dose will.
The acetate that is formed adds OH offsetting th phH decrease over time. So, the net decrease in pH from the dose itself works to zero but the initail drop can be precipitous and a serious concern, so, slow dosing during periods o photosynthesi is recommended for vinegar(acetic acid).
Bacterial activity on tahe organic produces CO2 thugh and this which has a noticeable long term effect on pH. At 400ml vinegar equivalents for 650 gallons ( I use a mix of vodka and vinegar), my pH feel from daily ranges of 8.15 to 8.35 to 8.0 to 8.2 and tha's with 24/7 kalk dosing. I made up for it with a CO2 scrubber eventually.