Top of water film

Do you have an overflow? Or is this just a box of water?

If you do have an overflow, how much does the water drop into the overflow? Ie.....1/8" or up to 1" and beyond.....
 
This is very common. An overflow will take care of this. If you don't have any surface overflow, then a strong surface agitation will be required to break this surface film - this film can inhibit gas exchange.

FWIW,
Kevin
 
Yep.. protein slick.. Very common on tanks without sumps or sufficient surface agitation. Point a powerhead towards the surface of the water to create some movement there to hopefully knock it down..
 
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