I've been dosing vodka for a month or more. I have a 65 G tank with 15G sump,40lbs of LR, I estimate my water volume to be around 70-75 Gallons. I'm running GAC and GFO. I do not have a refugium. I run a over sized skimmer rated for up to 160 gallons (swc cone 160) My nitrates have been at 20ppm and has not dropped once during my vodka dosing time. It has climbed a bit but not much. I am now at 3ML daily, am I doing something wrong?