IMHO I wouldn't use a buffer as it is usually only a short-term fix as you are experiencing. I would mix a small batch of RO/DI SW. Test CA, ALK,MG,SG. Then I would place one of your (GARF) rocks in it, wait 24hrs and test again. In the end, I would do a 100% WC in your nano and dose a 2-Part accordingly. (Randy Holmes-Farley in the 'Water Chemisrty' forum is most helpful, having many articles on water chemistry, including Alk, Ca, Mg, etc.) Once your water parameters are stable for "at least" a week, then you could proceed... Good luck!