I think that cutting off kalk dosing completely is the issue, couldn't you just have adjusted it to a lower setting? Seems like a drastic change in methodology in general, and drastic changes should never be made in a reef system when avoidable.
I personally have never really paid much attention to pH but 8.6 is not horrible as long as it doesn't stay there all day long. It's not where you want it to be if possible, but you should concentrate more on the long term trend. So backing off on the kalk, say by reducing dosing by 10-20% for a week, would have been my first step.
My experience with pH on a scrubber only system was that pH was more affected by the DT lights than anything else, the scrubber really just helped from pH bottoming out at night. So during the day cycle, when the scrubber is off, there is no photosynthesis occurring (at the scrubber, there is in the DT though) so how could the scrubber cause a pH to rise when it's not lit?
Granted that maybe your starting pH value at the point where the scrubber lights shut off and the DT lights come on is higher. So this may affect the overall peak pH value, but then you just have less reliance on Kalk for pH control. Now kalk for Alk and Cal levels, that's something different. Have you checked those? I'd be willing to bet that if you off Kalk these are dropping like a rock.