that is fine, then think of them as a lagoon substrate.the problem with that is that we now have to explain why we are not doing regular major substrate disturbing events. those pesky tropical storms. we are emulating nature right, or are we?
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That's the problem in sand bed discussions they seem to gravitate to extremes. It's either a deep sediment, or it's a shallow lagoon been kicked up by storms etc. It's actually 4-6" of sand in the bottom of a reef tank. I've never said anything about emulating nature or shown P flow within nature. I'm more interested in P flow with 4-6" of sand in the bottom of a reef tank connected to a body of water directly above it.
These discussions tend to describe a scenario where you have a perfect system. until you put 4-6" of sand in the bottom. Suddenly the addition of some sand has created a black hole with extraordinary powers that pull everything nasty into them. Until one day "something" bad happens. And the black hole is the culprit as it became full of "something".
ok, but still this is an increase in material. an increase in material is an increase in mass of the system. a sign of eutrophication. i guess this extra material could be trace elements, but that would lead to a toxic sludge, also something not wanted in our systems. any way you look at it, this material is not something we want in our systems indefinitely.
It could be mainly inert. We don't know. TOXIC sludge sounds better though!
when do you decide to take the trash out or flush the toilet? when does the trash can stop being useful for keeping trash? you can keep putting stuff in it when it is full, but it just falls to the floor. i think you are missing the role bacteria have in this and the sand itself. take the very top layer of a substrate. it is completely clean, and so is the water. now lets a touch of P to the water. to reach equilibrium the sand binds the P to reach equilibrium. now comes the bacteria. they take the P off of the sand, they fall into the substrate. now there is an open site for the P if the water and the sand are not in equilibrium. this poor bacteria with the P either lives, dies, or gets eaten. either way the P is now organically bound. the P is still sunk in the substrate and has not changed the equilibrium with the water column. this just keeps going on and on. the bacteria take the P, then do whatever. leaving a new place for P to be bound from the water column. of course some of this organically bound P will become inorganically bound by bacterial action, but as they are deeper in the substrate the harder it is for the P to reach an equilibrium with the water column because of all of the material in the way creating a barrier.
My trash can is a little different. Their is no "ecosystem" or chemical reactions reaching equilibrium states at work just me chucking lumps of plastic in each day until it is full. The analogy might sounds clever but really has no place in the discussion. By your description this P seems to be cleaved from calcium phosphate then just dumped into the sand.. more P binds, it's cleaved build up in bacteria live/dead. Your reactions always seem to proceed in one direction! NEGATIVE!
there is nothing wrong with that, and a substrate can be used to great affect in this manner for a while. a skimmer is not going to get it all, and in fact if the calcium carbonate bacterial tug of war did not exist our systems would not be alive. skimmers are fantastic exporters of organic P. i think they need to be bigger though. i am also a big fan of settling tanks, think empty live sumps. a place to see and easily remove accumulating detritus. conical setting tanks being better because of the nice valve on the bottom.![]()
You might as well pull the live rock too. The process you are describing for the P been bound to sand then bacteria taking it and building up endlessly is going to be happening on your live rock too as that is CaCO3.
that they contain. CO2 and carbonate are just other sources of elemental C for bacteria.
I'd like to see some references to marine bacteria typical in our tanks breaking down carbonate or bicarbonate to supply their carbon needs. Lots of elements contain carbon but it doesn't mean it is available to organisms. The reason organic carbon dosing seems to work is that there must be a limited availability of easily available carbon for use by bacteria in our tanks. The forms of organic carbon dosed are easily broken down for uptake by the organisms. If they were able to use carbonate theres a huge supply already in the water column!
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