The calerpa is producing CO2 at times like all plants do. The fact that your refugium is loaded with calerpa and I bet it is very healthy means that you are probably producing a ton of CO2 which is depressing the pH to 7.5.
As an analogy think of the calerpa as a camp fire which produces heat. The closer you get the hotter it is. Your pH probe is very close to the camp fire. The fact that the windows are open does not really have enough impact to diffuse the CO2.
Get a pH probe with a longer cable or get an extension. Try measuring the pH in the tank perhaps at the point where the water enters the refugium. This may be your highest pH point.