Amy, where did you get the DOWFlake from? Any local shops that carry it?
I heard that Home Depot carries Peladow but I don't think they have it constantly.
BRS has a 5 gal (35 pounds) of their Calcium Chloride, but it's about $56.
There is also a
recent thread at the Reef Chemistry forum about a certain CalTac Calcium Chloride which is food grade. I think this is what BRS sells. I have made some calls and no pharma companies seem to carry it locally. The nearest distributor that might have it is over at Grayson KY, but you need to be a company to even inquire about it. If anyone is interested PM me so I can give you the distributor's contact details.
As for Alkalinity, the bulk Arm & Hammer Baking Soda from Sam's should work. If you have high pH, you can use Baking Soda as is. If pH is low, you can bake the baking soda for at least an hour at 300F to remove the excess moisture and CO2. Follow the recipe in the link the Amy provided.
Here's the best calcium, alkalinity, and magnesium online calculator around:
http://home.comcast.net/~jdieck1/chemcalc.html
Btw, I've heard of 'special' 2 or 3-parts being sold locally. I would ask what's in them before you even consider them. The well respected ESV B-Ionic 2-part product for example, would list what each bottle contains which is quite admirable, since they tell you what you would get, in black and white. There are just too many impure ingredients out there that we should be careful with.