When I've had to run a lot of water out through the skimmer because I medicated the tank I've just added extra saltwater during a water change. Like take out 5 gallons and add back 6. By the time it evaporated down far enough to kick in the ato, the salinity was where I wanted it. The rest of the time my water changes keep it from getting out of whack even skimming pretty wet and carbon dosing.
I've heard of people just adding a teaspoon of salt to the sump when they dump the skimmer cup but that seems kinda risky.
The issue with topping off is evaporation isn't that stable. Depending on the season, room temp, humidity, etc. it's hard to use the ato to dose stuff that's more tricky than kalk. On top of that, skimming is probs not a steady salinity reduction either. It's only taking the salt attached to the poop, that could vary. Its not like you could just test the skimmate to see how much you lost each time.