Actually there should be a VERY safe and easy way to use, and harness this experience very safely, at least to you.
You guys are all thinking about 120v AC power. I went to boat school for corrosion among other things, and we studied "accelerated" galvanic corrosion from stray current. We hooked a pewter spoon to the + side of the battery, and a Bronze bar to the negative side of the battery. Between the bronze bar and the neg. terminal we had a 12v light-bulb, which would prevent a short circuit, by introducing a KNOWN load(amps) so you don't get a short-circuit. This voltags is quite safe to humans. You could easily stick both hand in and feel NOTHING, not even what you would get from licking a 9v battery. This was done in saltwater right out of the ocean.
Also, when you did this, you could "see" the electricity moving through the water. The trick about DC power is that it ALWAYS and ONLY travels in ONE direction. From the + to the -. Basically what happened, is that the electricity grabbed the dissolved salts and minerals to move the electricity. Basically making each attom a transferrable battery. That single particle would take a voltage charge, transfer to the negative side, and deposit the charge on that item. So you actually saw a slightly "cloudy trail" of electricity from the charged salts.
To make a long story short, I could EASILY see you using this method to "stun" a fish with a LOT of safety to YOU. Cannot speak for the fish. I would suggest using TRUE stainless steel as the 2 "rods" from which you would pass electricity. If you use any other material, whatever is connected to the + side will deposit microscopic pieces of itself in the water, which I already know some of can be toxic to fish. The current, or electricity will find the fastest path, or path of least resistance, and should travel a straight-line between the 2 "rods" so you WOULD have to get the fish to swim in-between them.