Randy I have yet to really see any yellowing of the water and I have been running a scrubber for 16 months. I can pull the water out of the tank into a white bucket at any given time and it looks like freshly mixed SW, perfectly clear. I mean perfectly.
Yellowing of the water is a result of insufficient lighting, which causes the roots of the algae (where it attaches to the screen) to die off. This was a common result of the past ATS designs which didn't have intense enough lighting to prevent die-off of the lower layers, which had the light blocked by the growth over the top of it. The advent of CFL and T5HO has virtually eliminated this problem.
In a properly built and maintained scrubber, this does not happen, and I feel I have concretely proved that to myself.
Yellowing of the water also is associated with cleaning of the algae screen while still in the tank, a practice of the past, no longer a problem.
I can't comment much on the buildup of DOCs in a tank that only runs a scrubber, other than to say that the tank I run a scrubber on has had nothing in it but a scrubber. I take that back, I did have one 100mL bag of Purigen in the sump, or maybe 2, I can't recall. In May, when the original tank developed a crack, I moved the contents, then moved again when the new tank arrived in November. Since May, nothing but scrubber. Tank water is crystal clear, so I don't know if that is a fair gauge of DOCs (I'm sure it's not the only one).
Conversely another 225g FOWLR that I have yet to put a scrubber on (it runs filter pad, bioballs, and a skimmer, and was newly set-up about 2 years ago) has nitrates off the scale and is yellow as h.e. double toothpicks. I'm curious myself to see what the effect of the scrubber has on this tank's conditions...