May be Suction Cup Caulerpa or Parasol Green Seaweed; depending on where your rock came from. I had it, also came out of nowhere I read it was harmless and the tang would eat it. My purple tang would not touch it, became a mat that covered the rock; by then had no other choice but to take out the rock, I took too long to act. You may get rid of it by plucking if detected soon; otherwise very difficult because some of the roots will stay attached and it will regenerate.