Ok I think I can help you, without the use of too many chemicals.
Your DKH is just fine, so that is not the cause.
I believe your PH is low because
A) you do not have enough oxygen in the room with the tank (is it a closed up room? Windows shut? If so try it with the windows open.
B)You don't allow for enough degassing, in which case put fans on the surface, drip CA effluent into a overflow of sorts, skimmer will add alot of air bubbles, open top tank will also help tremendously to raise ph.
You can also add kalk to your topoff water which will help stabilize the ph.
GL.
After you make these changes give it about 3 days.