Corals need 5 to 8 hours of good intense light for the photosynthetic process to run it's cycle. The zooxanthellae need roughly an hour to get the chemistry ready and started. Then for the next 4 to 6+ hours they will do photosynthesis and then shut down. Even if there is still intense light the process stops due to the genetics of the zooxanthellae. They have evolved over hundreds of thousands of years to a world on the reef where light is good and strong for 5 to 8 hours.
Yes sun up to sunset is 10 to 14 hours on a tropical reef. But the first 2 or 3 hours and the last 2 or 3 hours the sun is at such a steep angle to the water that really very little 'intense' light gets to any depth in the water.
So you can do a short or long sunrise, a good 4 to 8 hour midday and a short or long sunset.
As for fixture power settings, I can't help as I don't know what fixture you have, how deep your tank is, or what kind of corals you have. Start with lower power and work your way up. Or find a PAR meter so you can get real readings. Or get help from somebody with the same fixture you have.
***soapbox mode on***
Telling us the Reefer 250 may have a specific fixture and a specific tank depth, but leaving it for us to look up is foolish. You know what they are, so save us the effort and tell us. It would help you get better response from others here, IMHO.
***soapbox mode off***