Unfortunately not. My husband hates my tank and everything that goes with it.
Ouch. Don't you, in a way, "go with it?"
Well, it sounds like you understand that addition of the limewater will pull the pH up by taking up CO2 from the solution, and it should be added at night when pH is low. Dropping to 7.6 from 8.2 is a pretty big deviation. Most people keeping reef tanks that use limewater have the opposite problem, that pH tends to run too high. Do you recon your kit (or pH monitor) could be way off?
Could you add 2-part buffer in addition to limewater? With your pH running so low, you could push the TA (total alkalinity) up to 4 meq/L, or even higher, with additions of ESV B-ionic (or a similar 2-part) without getting too much calcium carbonate precipitating out . Like limewater, 2-part buffers push up pH. This is the easiest way to increase the pH (and keep TA and Ca++ balanced) that I can think of.
More direct gas exchange at the air/water interface should also help by allowing the tank to gas off CO2 faster. Moving air through the stand and hood should lower the ambient CO2 in the area where it is exchanging with your tank water. Directing more air and water flow at the water surface should also encourage gas exchange. Some new houses are sealed so tightly that they have problems with chronic high CO2, and in that case you'd have to solve that problem for increased agitation to improve CO2 release from the tank water.
So there are three easy answers:
1. pH isn't getting measured correctly to start with.
2. Add 2-part buffer to "consume" more CO2 in the solution if your TA isn't already high.
3. Allow the tank to gas off more CO2 by increasing air and water agitation at the surface, and venting more air through the tank and hood.
Consumption of CO2 by plants is, IMO, mostly a function of light intensity, available nutrients, and water flow by the plants. What plants you introduce to your tank and the volume of water where the plant production is occuring is secondary. I introduce desirable plants to my system because I'd rather grow them than have uncontrolled production of undesireable plants in my system. Chaeto is desirable but does not always grow well for everybody.
I guess what I'm saying is that I'm guessing that a 10G refugia could consume enough CO2 to bump up your pH, if the water flow through the refugia is enough and the light is bright enough. I'd also hedge my bets with a variety of algaes instead of just chaeto.
"Dyanamic Aquaria", Adey and Loveland, is one of the few books that discusses primary production and it's interelationship with water chemistry. It's too academic for most reefers but should be well within a RN's understanding. Some saltwater books by Steven Spotte have very good discussions of the mechanics of gas exchange, and these are often available through the library system. I have a xeroxed Spotte reference I could send as a .pdf next week that covers gas exchange, but not how photosynthesis effects tank pH.