I've always thought to dose for alk and cal so your levels are where you want them. For there you can start dosing kalk to maintain. My tank uses up alk before cal, so I'm constantly adding baking soda along with kalk. one gallon of rodi can only absorb 2 tsp of kalk, but I'd start with less and ramp up from there. It will drive up Ph, so be prepared. Vinegar helps, and it also adds carbon for the bacteria.
What worries me with that method is some days its more or less evaporation
If your only dosing 16ml a day then you would be dosing less than a quart of limewater a day. You wont have to worry about your evaporation. Set up a reservoir of whatever size you would like. Set the pump up to dose about a quart of limewater, use the calculator to find the exact amount, and your ATO will take care of the rest.
Since your using saturated limewater you can add as much pickling lime as you want to the reservoir. Add water when it runs low and when all the lime at the bottom dissolves add more. Just let it sit overnight after adding more water and lime so the precipitate can settle.
I'm actually planning on setting this up myself once I buy a dosing pump. It will reduce my 2 part usage and keep my alk steadier. I have the same evap issues you do so I won't be running it through my ATO.
What worries me with that method is some days its more or less evaporation