Lava rock is often air-puffed basalt scoria or rhyolite (I think that's the red one) which have metals in them you don't want.
Pumice, (easy to distinguish because it's light as styrofoam) is volcanic glass puffed up by air, similar to obsidian, which is the plain form. I wouldn't expect either pumice or obsidian to be all that reactive in water. But I are not a geologist!