If that is just one shim I would not call that terrible, not ideal of course but not terrible.
That in itself should not be an issue, and you should add other shims every 6" or so to take up the rest of that void along the length of tank.
I can't tell you you are secure on a 2nd floor w/out knowing what your framing is like or where positioned, hopefully near a bearing wall so framing is solid, hopefully spanning several joists and not parallel and only on one or two, but generally speaking a 75 should not be a big deal on a second floor w/ sound timbers