As long as you add it slowly, and only add an amount equal to your evaporation, I don;t think you'll have to worry much about ph. Many thousands of aquariums have used KW for replacing all the evaporated water to great results without a ph controller.
IMO the best way to add KW is with a peristaltic (or airlift/diaphragm, I guess) dosing pump. Simply estimate the amount of water you're evaporating and set the pump to dose that amount in a 24 hr period. You can put a piece of tape or use a sharpie to indicate your sump level, and check it every day for a while to get the correct amount dialed in. You might have to adjust it periodically, but that's no big deal.
Lots of other people have successfully used a tunze osmolator or other reliable sensor to push water through a KW reactor; my understanding is that submerging the osmolator pump in a tub of KW is pretty tough on the pump.
The problem of overdosing would be most likely encountered if you use a powerhead and float switch; the float switch can easily stick on, and the powerhead will deliver KW too quickly to your sump. This is the big advantage of the dosing pump IMO.