So here's my mad science thinking, and it may apply to older tanks with a huge coral load.
For the sake of discussion, lets say my daily Alk usage is 2 KH. If I dose that over 24 hours then my morning Alk will be 8, end of light cycle will be 7, and then it will climb to 8 by the next morning if we assume corals do not use any Alk at night (which is what many are confirming). This assumes I'm dosing enough for 1KH during the 12 hour day and another 1 KH overnight so the drop is only half of the total daily usage.
Maybe 1KH is no big deal, but what if My Alk usage is something crazy, like 6 KH daily?
Suddenly I'm doing daily swings from 9KH in the morning to 6KH in the evening. That's pretty flipping huge! As you can see, continuing 24 hour dosing and continuing to raise the amount as the tank grows actually decreases stability due to the difference in day/night usage.
That's my theory. I don't have an expensive 24/7 Alk doser but I am doing numerous tests here for the next day to see if I see the pattern. Because my KH spiked to 9 my doser is off but Kalk is still being added via my timed topoff every 15 minutes. It's saturated Kalk so using the calculator and figuring my usage is about .8 gallons daily, this equates to 0.6KH of Kalk added daily.
So far my daily measurements with Salifert, backed up by Hanna, are:
9.3 at 4pm
8.8 at 6:30pm
8.6 at 8:30pm
8.5 at 6AM
8.1 at 4PM
7.9 at 6:30 PM
Next reading at 8:30 after the white lights dim for the evening. Blue LED stays on until 10 so that probably accounts for some of the overnight Alk usage.