I will disagree with the comment that High Kelivin White LED's cover all the blues 420,440,460.and 480.
I agree. What I said was "High kelvin white chips include a broad spectrum of blues, greens and reds that you will not see in task 6,500-10,000k task lighting.". Also 420 is violet, not blue.
In many cases they are nothng more than 6,500K chip with the longer wave lenghts filtered out. Remember when the rate a chip they are rating it on the ratio of red, green, blue.
They are rated by how "blue" they are. Phosphor coating does not filter out light. It converts it to other spectra. Phosphor coated high kelvin chips are native blue chips, not 6,500k chips. They simply lack the phosphors that are cherished for their bright green colour. Blue light is converted to green and red to create a white chip.
It is much eaier to get a higer amount of 460nm Blue than it to get an apreciable amount of 429 nm "blue"
Of course, violet chips (429nm) are not blue chips with phosphor coating, they are a dedicated chip.
This is why I cannot understand why somone will use a 20,000K chip then suplement it with Red chips and even in some cases amber and yellow chips.
I have only seen yellow chips used with 6,500k fixtures which are already too yellow. I'm not sure what the logic is behind amber or yellow chips. The people who use them haven't given any reasoning that I have come across. 20,000k white chips have adequate yellow light.
Yes there is an isue with LED lighting with wave lenghts of 440 nm or less.
I don't know what issue you are referring to. Cost and availability is the main reason why these (violet) chips are absent in many mass produced fixtures.
There is also an issue with the wave lenghts in the 490 to 500 range as no chips put out a strong spectrum in that range.
490 - 500nm chips are readily available.
But with Royal Blue 454 (444 to 464 and Blue 460 (450 to 470) we are covering a majority of the blue range and the addaptibility of coral can easily compensate for anything missing near that range.
I don't want to single out any brands, but there are widely reported deficits with blue, royal blue and 6,500k chip mixes. You can keep a reef tank with that mix, but it will not equal the spectrum of metal halide, fluorescent or natural sunlight. There is a reason why 6,500k MH and fluorescent lights haven't been popular for over 20 years. They are popular in the reef LED industry due to heavy marketing for task lighting. High lumen/watt ratings sells lights. Unfortunately, this metric is based on a scale of human eye sight and not coral requirements.
If you truely want to cover that range better the thought of combining HO T-5 bulbs like ATI Blue Plus, or URL Atinic plus White will do a better job than any individual LED.
Fluorescent lighting has a broad spectrum, but there are many faults such as colour banding, no shimmer, artificial/clinical appearance, short lifespan, electrical hazard and maintenance issues (too close to the water surface), surface glare, and excess light cast upon the viewing panels (algae growth).
LED is clearly the easiest way to provide the desired broad spectrum and colour mixing.