I can usually tell when it's time to change the media in my phosban reactor when I notice that I have to clean algae off the glass of the tank more often. Usually it's about once a week, but when I notice a slight algae film that I have to clean off every two or three days or so, I know its time to change the media. Certainly not as precise as testing the water with a really good phosphate test kit, but it works.