It's like a three-legged stool, only kind of a magical one in which one leg is the standard. If you have to adjust chemistry, you can pour alk and cal in with no lasting result...unless you raise mg first. Raise that to about 1300 (which gives it some wiggle room) and THEN when you add buffer and calcium, the readings will stay where you put them until the mg runs out. I think the trick is that the alk thing is just buffer, which controls acidity/alkalinity of the seawater, which is how able it is to dissolve calcium, which is the name of the game. When you supplement calcium to the hungry stony coral, it sucks it up fast, but kalk goes on pouring calcium into the tank, and the buffer allows the water to stay at the right ph range; and the mg helps hold the buffer steady...I'm far from sure of that scenario, because I was NOT my chemistry prof's star student, but that's operationally how it works, at least.