It’s quite unfair and misleading that bioballs/ceramic rings have been coined with the term “nitrate factoriesâ€Â. Nitrates are created by nitrites, which are created by ammonia, which comes from fish pee/poop. If your tank produced no fish/ammonia, then your bioballs wouldn’t produce any nitrates on their own!
Thinking along those lines, then LR would also be nitrate factories, because they also break down ammonia into nitrates. But yes, becuz LR have anaerobic environment in the deep layers, it’s able to process some nitrates. But from my experience, its denitrating capability is not great.
I used to run a lightly stocked 50g full reef with 100lbs of mixed indo/tonga LR, but my nitrates still crept up over time.
Bioballs do not provide an anaerobic environment for denitrating bacteria to thrive, thus the nitrogen cycle stops at nitrate.
Instead of replacing the bioballs with LR, you should consider adding a sulfur denitrator. I’m now running a heavily stocked 200g FO with big angels, triggers and tangs with zero LR. My big fish have so much more room to swim. I run 40+ liters of ceramic rings and a Schuran sulfur denitrator. My nitrates are never detectable. I still religiously change water once a month, but my fish never have to deal with even 1ppm of nitrates. Even if I dropped in 400lbs of LR, my nitrates would still eventually creep up over time.