Saturated kalkwasser has about 800 ppm of Ca and 2000 ppm (40meg/l, 112dKH) of Alk. So, it will add both Ca and CaCO3, but is limited by how much you can add in your top off water every day. So, if you have to increase your Ca or Alk by any substantial amount, you should use a two part method. Or consider using a reactor.