I was wondering that how long do they last and if it is worth getting it.
A RO/DI unit is basically some tubing, some housings for filters and membranes and a rack to hold it neat. These almost never wear out, though the tubing can have issues, and every single part is available.
The main cost of any RO/DI unit is the filters, membrane and resin. For normal units, filters can run $10-40 each, resin is about $10-20 and the membrane is $50-75. In a new, $150 unit, the hardware (non-consumables) is probably about $40-50 of the price, the consumables are the rest.
In a used unit, the hardware is what you are buying and all consumables are suspect. Membranes are especially suspect if the unit is dry, they need to be stored wet. Filters and resins are suspect because you don't know what water or other material has been run through it. So to recondition a used unit that sold for $150 new will cost about $70-100, assuming hardware is fine.
Personally, that means a RO/DI unit selling used, in "perfect" condition, would be worth less than $50 to me, more like $25 or so. You can do similar math with the exact unit you're considering, that's just my range.
Jeff