I'd say freezing is most defintly not humane. I think it is a common answer but use some logic. Cold-blooded animals have to regulate their body tempatures. Unlike mammels who body takes care of it for them. So they have to be more sensitive to heat/cold. They need their bodies to be a certian temp when they feel that the temp isn't right they must move to a different location. I know people don't think of fish this way but snakes and lizards are cold-blooded too and we all know a snake will go from the shade to sun if it gets too cold and vica versa. Fish behave in the same mannor. As well as a saltwater enthusiast I'm a fisherman (I eat my fish I don't catch and release please don't flame PM me if you have issue with fishermen and I'll explain my reasoning behind it) I know being a fishermen if its hot out like now I'm better off fishing deep. Why? The fish know they are hot and they go deeper to cool themselves off. So freezing I would say while easiest on the human is not on the fish. Mammals shiver to create heat when we get cold the fish probably has everything in it telling it it needs to find more warmth. Sounds horrible to me. Plus I would venture that they probably sufficate before they freeze so you might as well just throw it out of the tank. While the crushing it with tire/rolling pin sounds unpleasant as long as you started at the head you would crush its brain and that would end it right there. The clove oil sounds reasonable too. As long as the fish dies quickly I would assume it would be like a person walking in to a room filled with carbon monoxide they would die and not realize it. Electricution and or cooking is defintly out of the question. So in my humble opion put freezing at the bottom and if you can handle it crushing at the top or maybe clove oil.