I'll share with you the words I live by when it comes to reefing. If it's not coral, and I just don't know what it is, I remove it ASAP and flush it. Why? Not bragging, but I have thousands of dollars invested in my entire setup, tank, rock, corals, hardware etc, I'm not going to risk having an unknown in my tank that could potentially be devastating if gone unchecked. Sure it may be overkill, but I'd much rather be safe than sorry. That's just me, and I don't want to force that on anyone else, it's just words that I live be.
Mucho Reef
BTW, I have seen this before in my tank, there is a name for it, I'll check with a friend who had it and IDed it. It was brown when I had a patch of it. It peels off very easily if it's the same stuff. I will get back to you if I can get a name.