I have very little facts to back this up but, I believe there is truth to flourescents changing spectrum over time.
Have you ever looked at two of the exact bulbs, side by side, one old one new? They look significantly different, in fact many would swear they are differetn colors.
Why?
My theory:
The phosphoros themselves do not change in a bulb over time. Have you ever noticed that most flourescent lamps have a very pronounced peak at a certain wavelength? What happens is the peak (usually around 420 to 480Nm) is what degrades the most over time. Then the percentage of light changes. For example a lamp may have 80% of its energy around 420Nm and it looks like an actinic bulb, as the lamp degrades the 420 peak degrades the most, then the lamp has maybe 60% of its peak in the 420 Nm range. Thus the bulb looks more yellow.
I believe there is some truth to what people on both sides of the story have to say. But to really understand it one has to have an unbiased in depth understanding of htese lamps age.