That's an interesting thought. They do need rest, however, and they seem to almost sleep at night. A few will be lazily swimming around, but most will hang near the bottom or along the edges at night (moreso that what I just mentioned about about them starting to do that more anyway.)
I have not monitored pH with this batch, but with the last batch I did the aeration test several times in the evening/morning/midday with no significant change. I also put a probe in for a couple of nights after the last batch had their Day 9 dieoff, and the pH did not drop very much at night.
Normally, I have a pH probe on the other tank in the room and only get a .01 to .02 drop at night. So Cal house; no such thing as "airtight" or "insulated" and I keep the window in that room cracked anyway. (Funny sidebar -- I got new windows, and with the windows cracked about 2", I still have less drafts from the new windows than the last ones!)
I also buffer the water changes, which are every two days. I think that helps a lot.
A moonlight might be an interesting experiment. I don't think I have a good grasp of normal yet, so I don't know if running such an experiment would be productive right now. Maybe in another couple of batches?