<a href=showthread.php?s=&postid=8450048#post8450048 target=_blank>Originally posted</a> by Randy Holmes-Farley
Different folks may define contact time differently.
So back to contact time. Somehow one must account for how long the air/water interface is in contact with the dirty water, because increased time allows for molecules from farther and farther away to actually randomly contact the interface and bind. The binding itself is not that time dependent (at least on these time scales and perhaps excluding denaturation of proteins), but rather it is the time taken to get to the interface.
That said, my point above is that if you have a short contact time, you deplete the near interface areas of organics and do not allow time for the father away ones to reach the surface, and then you replace that bubble with a new one, you HAVE NOT reset the clock and need to wait a long time again, because the new bubble does not immediately have the near surface area depleted of organics. It can quickly start binding nearby organics right away.
This is a point that many folks seem to misunderstand, IMO. There is not a long time for the binding to take place. It is time for diffusion to take place. I agree that if it took a second or a minute or 5 minutes for the actual binding to the interface to take place, then contact time itself would be critical. Tha tmight ahppen for certain very complex proteins, but I do not believe that plays a dominating role in reef aquaria, and difussion is the key, not the reaction itself. So contact time is not important, IMO. It is the amount of air/water interface present that is actually important, and the rate at which it is turned over. Increasing dwell time may actually increase the amount of air/water interface present, depending on how it is done, but dwell or contact time itself is not a key parameter (IMO).