I agree it shouldn't be a problem . I wouldn't expect the bicarbonate uptake to effect pH as the equilibration of the carbonate continuum is instantaneous. The photsynthetic activity involving CO2 uptake should raise pH not withstanding bicarbonate uptake .
On the other hand CO2 hydrolyzation takes time ( about 23 seconds)per Randy's article) .
So .it's not just a one step two step process by the algae as claimed in the ATS endorsement detour. It's a poor extrapolation giving a misleading impression, imo. That is, not all the available CO2 is used before bicarbonate by those organisms that can use bicarbonate for CO2.Bicarbonate uptake via protein transporters or enzyme activity probably occurs somewhat independently of the direct CO2 uptake as the CO2 is small enough to go through the cell membrane without help but may vary in localized concentrations near the consuming organisms.
The idea with a CO2 scrubber or fresh air solutions for pH is much different than uptake via photosynthesis since the first 2 focus on limiting the CO2 in the air entering the tank water; not on uptake assumptions dependent on photosynthetic organisms which can vary in their consumption considerably due to a number of variables like ph, light, iron,space.competition, growth et alia.
Having said that maroalgae refugia on opposite photo period can clearly help nnightime pH drops and help offset nightime hypoxia.Unfortunately space and light are requisites for algae export systems whether they float, are on a screen, are in a bare bottom bin or in a water fall. Higher level nutrients also encourage algae growth but most of us don't want more N and P or Fe in an effort to lower CO2.They also contibute organic matter that should be accounted for. Coral growing on oppsoite photoperiod can do much the same.