I have a question about the bio-balls. I have read that they trap a lot of nitrates and this can have negative consequences on the water. Isn't it a good thing if they trap the nitrates? The bad thing is if you don't clean the bio-balls and they get too clogged up? They sound like a furnace filter to me...a great device but detrimental to your furnace/air quality if you don't clean/replace it regularly.
Thanks, John
There was an advertising campaign back in the mid 80's claiming that the bio ball media used for sewage treatment was ideal for fostering the growth of nitrifying bacteria in aquarium filtration devices (wet/dry filters). These bacteria convert toxic ammonia to nitrite, then further reduce the nitrite to an even less toxic nitrate. The problem with the sales pitch is that it was just that, a shallow marketing campaign. Scientific studies show that it takes eight feet of bio balls to achieve the same bacterial culture and subsequent nitrification that you get with just 8 inches of sand.
Biological media have two critical factors that govern their efficacy 1) surface area (real estate) and 2) void space (air gaps for gas exchange). Bio balls offer an abundance of void space for processing raw sewage, but greater surface area is the key to ammonia reduction in aquarium applications.
Reef tanks have more than enough surface area for nitrifying bacteria to populate so any form of biological filter is redundant. Live rock and a sand substrate is all you need. The problem with relying too much on biological filtration is an imbalance can result in residual nitrate. Nitrate restricts the growth of corals at higher concentrations, but is a necessary nutrient for corals nonetheless.
The suggestion of using live rock in the wet/dry filter in place of bio balls is actually counterproductive if one is trying to avoid nitrification, as bio balls are more efficient than bio balls. Bio balls do assist with gas exchange, stripping Co2 from the water and increasing dissolved oxygen, but with proper flow dynamics this is not necessary.
The focus on biological filtration in reef tanks is denitrification (the group of bacteria that convert nitrate into nitrogen gas and nitrite) which is achieved with sand beds, sulphur bead filters, solid vodka media, slow flow denitrators, ion exchange resins, nutrient export (refugia), and circumventing the nitrification process in the first place through the use of mechanical filtration, UV sterilization, ozonation, foam fractionation (protein skimming), and carbon dosing (vitamin C, lactose, methanol/vodka, or glucose).
So to answer your question, nitrate doesn't get "trapped" in bio balls, but it does get produced their. They don't require cleaning as this would remove the biofilms (slime coat of bacteria) that form their. Wet/dry filters should have a mechanical prefilter, but detritus works its way through anyway.