For instance hydrogen sulfide breaks down very quickly when it reaches oxygenated areas, so unless you go digging deep in your sand bed it won't be an issue. It also is extremely odiferous so you'll know right away if it is getting released. If you can't smell it, there is not enough of it being released to harm anything. Given continued presence of sand worms it would have no greater concentration in an old tank than a 2 year old tank.
Define quickly. Several hours to a day is long enough to do a lot of damage.HS- can be deadly in parts per billion so a good nose isn't a safe indicator,imo.. While most can smell it at low concentrations human sensitivity to the odor varies as does the H2S portion.
http://reefkeeping.com/issues/2005-12/rhf/index.php
from it:
Hydrogen sulfide has a strong "rotten egg" smell. The odor of H2S can be detected in the air by humans at levels as low as 0.5 to 300 ppb. The large variation in range indicates that some individuals are very much more sensitive to it than others.
and
is by inhibiting a mitochondrial enzyme called cytochrome c oxidase. It can be inhibited at hydrogen sulfide levels in solution as low as 30 ppb.12 Such inhibition limits the ability of mitochondria to produce energy for cells. Another enzyme, catalase, is inhibited at concentrations of 6,000 ppb.12 Other mechanisms of toxicity are also likely, and have recently been studied.
and
sediments are the most likely place for hydrogen sulfide to be produced in a reef aquarium.
marine sediments often accumulate hydrogen sulfide and deplete in sulfate. This zone often starts a few centimeters below the surface, and can extend up to a meter or more before the sulfate is fully depleted. Below that depth, other processes take place, such as methane production.
and
I'll comment on clumping/clogging and other points a bit later. It's not as simple as maintaining aquarium ph.
Define quickly. Several hours to a day is long enough to do a lot of damage.HS- can be deadly in parts per billion so a good nose isn't a safe indicator,imo.. While most can smell it at low concentrations human sensitivity to the odor varies as does the H2S portion.
http://reefkeeping.com/issues/2005-12/rhf/index.php
from it:
Hydrogen sulfide has a strong "rotten egg" smell. The odor of H2S can be detected in the air by humans at levels as low as 0.5 to 300 ppb. The large variation in range indicates that some individuals are very much more sensitive to it than others.
and
is by inhibiting a mitochondrial enzyme called cytochrome c oxidase. It can be inhibited at hydrogen sulfide levels in solution as low as 30 ppb.12 Such inhibition limits the ability of mitochondria to produce energy for cells. Another enzyme, catalase, is inhibited at concentrations of 6,000 ppb.12 Other mechanisms of toxicity are also likely, and have recently been studied.
and
sediments are the most likely place for hydrogen sulfide to be produced in a reef aquarium.
marine sediments often accumulate hydrogen sulfide and deplete in sulfate. This zone often starts a few centimeters below the surface, and can extend up to a meter or more before the sulfate is fully depleted. Below that depth, other processes take place, such as methane production.
and
I'll comment on clumping/clogging and other points a bit later. It's not as simple as maintaining aquarium ph.