It turns out it was Randy who was the expert, I guess we can rely on him. Here as an excerpt from Randy's "Hydrogen Sulfide" article that Weatherman posted for us.
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Hydrogen sulfide has a strong "rotten egg" smell. The odor of H2S can be detected in the air by humans at levels as low as 0.5 to 300 ppb. The large variation in range indicates that some individuals are very much more sensitive to it than others. Interestingly, humans may become insensitive to the odor at concentrations above 100,000 ppb. For this reason, individuals working with the gas need to be aware that they may no longer smell hydrogen sulfide when it is present at life threatening concentrations. When I have used hydrogen sulfide in the laboratory, I have worn sensor badges that indicate exposure to concentrations that may be too high to smell, warning that action needs to be taken immediately (fortunately, I was very careful to work in a chemical fume hood and never smelled, nor was I exposed to any hydrogen sulfide).
When dissolved in water, the smell depends strongly on pH (which determines how much is in the volatile, hence "smellable," H2S form). Humans often can just detect hydrogen sulfide odors when the concentration is above about 0.029 ppb in freshwater. In seawater at pH 8.2, where only 6% of the sulfide present is in H2S, this odor threshold is likely higher, perhaps on the order of 20-fold higher (0.6 ppb). Fortunately, that threshold is below the lethal limit of many aquatic organisms (usually above 5 ppb; sometimes as high as 50,000 ppb), so odor often can be detected by humans before hydrogen sulfide rises to acute, lethal concentrations in reef aquaria.
That whole article is a great read, I've read it several times before, but I think I got more out of it this last time. Kind of like an exceptionally good movie !
Randy also explains that Hydrogen Sulfide processing begins in as little as 1 1/4" of depth, and can extend to 40" depth, while going thru various other chemical processes.
For anyone interested in more info. in this regard, Weatherman's link to Randy's article is really a "must read".
> Barry
