Interesting. Well, it looks like you have a PO4/NO3 imbalance somehow. Most people seem to have the opposite problem.
Thinking out loud, something is taking out PO4 in your system. If this is you macro algae, than it also is taking out some NO3, but not all of it. If this is your vodka dosing, same problem.
I would try foods high in phosphates, nori for one, more of it. In an empty tank like yours I would also experiment with PO4 additives, such as triple super phosphate fertilizer or some commercial aquarium PO4 additive. Bottom line though, you would need to restore the balance somehow for NO3 export to start working again.
Also, I wouldn't put fresh air and pH high on priorities when NO3 is 20-30ppm for small SPS frags.