First of all - I hope you practiced safe trading and did a zoa dip before putting them in your tank!
Second - I never acclimate zoas - I just do the zoa dip and put them straight in.
In answer to you actual question; IMPE it seems to vary a great deal depending on the specific zoa. Most of my new frags open up within an hour or so or being put in the main tank under actinics (always start them off under actinics only if you can.) Some take a day or two. I've had some take a week. Rarely, one may never open at all and just melt away. You can try moving them around to give it more or less current or light and also spot feeding it a bit. (Sometimes they'll open up when there's food around.) You should check to see if you can find something irritating them (pest, fish, fungus, algae, etc.) Sometimes there's not much you can do except ensure a good home for them and keep you fingers crossed.